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骆驼集团蓄电池销售有限公司

CAMELGROUPBATTERYTRADINGCO.,LTDSEALEDMAINTENANCEFREEBATTERY

MATERIALSAFETYDATASHEET

SECTION1-CHEMICALPRODUCTANDCOMPANYIDENTIFICATIONManufacturer’sname:CAMELGROUPBATTERYTRADINGCO.,LTDAdress:NO.4ZHUIRIROAD,HI-TECHINDUSTRIALDEVELOPMENTAREA,XIANGFAN,HUBEI,CHINApostcode:441003Tel:+2Fax:+5SECTION2-COMPOSITION/INFORMATIONONINGREDIENTSmaintechnicalspecificationforLow-maintenanceBatteries(WithoutAcid):Batterytype58827RatingvalveV12RatingcapacityAh88NetweightKG22CCAA640Dimension(MAX)L*W*H*TH(mm)352*175*190*PALHAZARDOUSCOMPONENT(S)(chemical&commonname(s)

HazardCategory%ACGIHTLVOSHAPEL-TWA

7439-92-17440-36-07440-38-27664-93-97440-70-27440-31-5

Lead/LeadOxide/LeadSulfateAntimonyArsenic

SulfuricAcid(BatteryElectrolyte)CalciumTin

Acute-ChronicChronicAcute-Chronic

Reactive-OxidizerAcute-ChronicReactiveChronic

55-70%0-5%<1%20-35%<0.15%<0.3%

0.05mg/m30.5mg/m30.01mg/m31.0mg/m3Notestablished2.0mg/m30.05mg/m30.5mg/m30.01mg/m31.0mg/m3Notestablished2.0mg/m3NOTE:PEL'sforindividualstatesmaydifferfromOSHAPEL'ithlocalauthoritiesfortheapplicablestatePEL's.

OSHA-OccupationalSafetyandHealthAdministration;ACGIH-AmericanConferenceofGovernmentalIndustrialHygienists;NIOSH-NationalInstituteforOccupational

SafetyandHealth.

COMMONNAME:(Usedonlabel)Maintenance-freeBatteries(TradeName&Synonyms)ChemicalFamily:

Lead-AcidStorageBattery,WithAcid;

Low-maintenanceBatteriesWithAcid

ToxicandCorrosiveMaterialMixture

Formula:LeadandAcid(electrolyte)

ChemicalName:Lead-AcidStorageBattery

Declare:MaintenanceBatteries,WithAcid(Electrolyte)anddoesnotHg;

NOTE:beforeusing,immitBatterySulfuricAcid(BatteryElectrolyte)Densitymustequalto1.28(25℃)SECTION3-HAZARDIDENTIFICATIONComponentsDensityMeltingPointSolubility(inH2O)OdorAppearanceNO.4ZHUIRIROAD,HI-TECHINDUSTRIALDEVELOPMENTAREA,XIANGFAN,HUBEI,CHINAPOSTCODE:441705Website::+2FAX:+5骆驼集团蓄电池销售有限公司

CAMELGROUPBATTERYTRADINGCO.,LTDLeadLeadSulfateLeadDioxideFiberglassSeparatorContainer(ABSorPP)11.346.29.4N/AN/A327.4°C1170°C290°CN/AN/ANone40mg/l(15°C)NoneSlightNONENoneNoneNoneToxicNoOdorSilver-GrayMetalWhitePowderBrownPowderWhiteFibrousGlassMembraneSolidPionContactwithinternalcomponentsifbatteryisopened/tofreshairandprovidemedicaloxygen/atelyflushwithwaterforatleast15minutes,ciousdrinklargeamountsofwater/N5-FIREFIGHTINGMEASURESComponentsFlashPointLeadHydrogenNone259℃ExplosiveLimitsNone4%-74.2%Emithydrogenonlyifovercharged(Voltage>2.4VPC).Toavoidthechanceofafireorexplosion,uishingMedia:Drychemical,Foam,CO2FiberglassSeparatorABSPPNoneNoneN/AN/ADanger:aturesover300°C(572°F)offire:wearpositivepressureself-containedbreathingapparatus.N/AN/offire:tsNO.4ZHUIRIROAD,HI-TECHINDUSTRIALDEVELOPMENTAREA,XIANGFAN,HUBEI,CHINAPOSTCODE:441705Website::+2FAX:+5骆驼集团蓄电池销售有限公司

CAMELGROUPBATTERYTRADINGCO.,LTDFlashPointNotApplicableFlammableLimitsinAir%byVolume(Whencharging)Hydrogen(H2)Lower4.1%Upper74.2%lengasandsulfuriclFireandExplosionHazardsasperACGIHIndustrialVentilation:AManualofRecommendedPracticeandNationalFireCode,1980Vol.1,P.12,B-9,beflammableorexplosivewhenmixedwithair,oxygen,dHydrogenVentilatechargingareasUseNIOSHapprovedself-containedbreathingapparatus(SCBA)andfuldmistandExtinguisherMediaClassABC,CO2,HalonAuto-IgnitionTemperaturePolypropylene6penflames/sparks/othersourcesofriskoffireorexplosion,keepsparksorothersourcesofignitionawayfrombatteriesanddonotallowmetallicmaterialstosimul/ICACIDREACTSVIOLENTLYWITHSECTION6-ACCIDENTALRELEASEMEASURESProceduresforCleanup:Stoprelease,ontactwithanyspilledmaterial.

entry.

Limitsiteaccesstoemergencyresponders.

Containspill,isolatehazardarea,anddeny

PlacebatterySodium

Neutralizewithsodiumbicarbonate,sodaash,limeorotherneutralizingagent.

eofcontaminatedmaterialinaccordancewithapplicablelocal,onate,sodaash,sand,limeorotherneutralizingagentshouldbekepton-siteforspillremediation.

PersonalPrecautions:Acidresistantaprons,bootsandprotectiveclothing.

ateenclosedareas.

ANSIapprovedsafetyglasseswithsideshields/faceshield

EnvironmentalPrecautions:Leadanditscompoundsandsulfuricacidcanposeaseverethreattotheenvironment.

soil,andairshouldbeprevented.

Contaminationofwater,

SECTION7-HANDLINGANDSTORAGEPrecautionstobeTakeninHandlingandStorage

Keepawayfromflamesduringandimmediatelyaftercharging.

Combustionoroverchargingmaycreateorliberatetoxic

andhazardousgasesandliquidsincludinghydrogen,sulfuricacidmist,sulfurdioxide,sulfurtrioxide,stibine,arsineandsulfuricacid.

Storebatteriesincool,dry,well-ventilatedarea.

Donotshortcircuitbatteryterminals,orremovevent

tbatteryfromphysicaldamage.

OtherPrecautions

nfromeating,drinkingorsmokinginwork

Laundersoiledclothingbeforereuse.

ghlywashhands,face,neck,andarmsbeforeeating,dbatteriescontainhazardoussulfuricacidresidue.

SECTION8-EXPOSURECONTROLSANDPERSONALPROTECTION

NO.4ZHUIRIROAD,HI-TECHINDUSTRIALDEVELOPMENTAREA,XIANGFAN,HUBEI,CHINAPOSTCODE:441705Website::+2FAX:+5骆驼集团蓄电池销售有限公司

CAMELGROUPBATTERYTRADINGCO.,LTDRespiratoryProtection

(SpecifyType)

AcidgasNIOSHapprovedrespiratorisrequireposurelevelsareunknownorwhenfirefighting,wearaself-containedbreathingapparatuswithafullfacepieceoperatedinpositivepressuremode

Ventilation

airevery15min.

ProtectiveGloves

Wearrubberorplasticacidresistantgloveswithelbowlengthgauntletwhenfillingbatteries.

OtherProtectiveClothingorEquipment

EyeProtection

LocalExhaust

WhenPELisexceeded.

Mechanical(General)

Normalmechanicalventilationrecommendedforstationary

applications.

ANSIapprovedsafetyglasseswithsideshields/goggles.

VentilationasdescribedintheIndustrialVentilationManualproducedbytheAmericanConferenceofGovernmentalIndustrialHygienists,shallbeprovidedinareaswhereexposuresareabovethePELorTLVspecifiedbyOSHAorotherlocal,-resistantrubberorplasticapron,wash.

Safetyshower

SECTION9-PHYSICALANDCHEMICALPROPERTIES

PercentVolatilebyVolume(%)WithoutAcid

MeltingPointPolypropylene>320oFxVaporDensityHydrogen(Air=1):0.069EvaporationRateNotApplicable

SolubilityinWaterAppearanceandOdor

Battery:

Polypropyleneorhardrubbercase,solid;

At

STP

(internal):Gray,metallic,solid;Brown/greyoxide

SECTION10-STABILITYANDREACTIVITY

Stability

UnstableStable

ConditionstoAvoid

Incompatibility(MaterialstoAvoid)HazardousDecompositionProducts

Hightemperatures-casesdecomposeat>320°verchargingandsmoking,orsparksnearbatterysurfaceandrapidovercharge.

Sparks,Openflames,Keepbatterycaseawayfromstrongoxidizers.

Anexplosivehydrogen/dioxide(CO2)andcarbonmonoxide(CO).toxicorrespiratoryirritants.

Combustioncanproduce

Moltenmetalsproducefumesand/orvaporthatmaybe

HazardousPolymerization

MayOccurWillNotOccur

Donotovercharge

SECTION11-TOXICOLOGICALINFORMATIONGENERAL:Theprimaryroutesofexposuretoleadareingestionorinhalationofdustandfumes.

NO.4ZHUIRIROAD,HI-TECHINDUSTRIALDEVELOPMENTAREA,XIANGFAN,HUBEI,CHINAPOSTCODE:441705Website::+2FAX:+5骆驼集团蓄电池销售有限公司

CAMELGROUPBATTERYTRADINGCO.,LTDACUTE:

INGESTION/INHALATION:Exposuretoleadanditscompoundsmaycauseheadache,nausea,vomiting,abdominalspasms,fatigue,sleep

disturbances,weightloss,anemia,andpaininthelegs,damage,aswellasanemia,C:

INHALATION/INGESTION:Prolongedexposuretoleadanditscompoundsmayproducemanyofthesymptomsofshort-termexposureandmayalso

causecentralnervoussystemdamage,gastrointestinaldisturbances,anemia,msofcentralnervoussystemdamageinclude

fatigue,headaches,tremors,hypertension,hallucinations,dysfunctionandpossibleinjuryhasalsobeenassociated

cover-exposuretoleadhasbeenimplicatedasacausativeagentfortheimpairmentofmaleandfemale

reproductivecapacity,butthereis,atpresent,ntwomenshouldbeprotectedfromexcessiveexposure.

Leadcancrosstheplacentalbarrierandunbornchildrenmaysufferneurologicaldamageordevelopmentalproblemsduetoexcessiveleadexposureinpregnantwomen.

SECTION12-ECOLOGICALINFORMATIONInmostsurfacewaterandgroundwater,leadformscompoundswithanionssuchashydroxides,carbonates,sulfates,,yoccurassorbedionsorsurfacecoatingsonsedimentmadisstronglyretainedinLeadmaybeimmobilizedbyionexchangewithh(wheninthedissolvedphase)isbioaccumulatedbyplantsandanimals,SECTION13-DISPOSALCONSIDERATIONSWasteDisposal

wholescrapbatteriestodistributor,s7617594.

ForinformationonreturningbatteriestoConcordeforrecyclingcall+860710

Forneutralizedspills,placeresidueinacid-resistantcontainerswithsorbentmaterial,sandorearth

anddisposeofinaccordancewithlocal,tlocaland/orstateenvironmentalofficialsregardingdisposalinformation.

SECTION14-TRANSPORTINFORMATIONUNDOTPROPERSHIPPINGNAME:Batteries,wet,ARDCLASS:UMBER:KINGGROUP:IIINO.4ZHUIRIROAD,HI-TECHINDUSTRIALDEVELOPMENTAREA,XIANGFAN,HUBEI,CHINAPOSTCODE:441705Website::+2FAX:+5骆驼集团蓄电池销售有限公司

CAMELGROUPBATTERYTRADINGCO.,EL:CorrosiveIMOPROPERSHIPPINGNAME:Batteries,wet,::UN2794IMOLABEL:CorrosiveIMOVESSELSTOWAGE:AEms#-F-A,S-BIATAPROPERSHIPPINGNAME:Batteries,wet,::UN2794IATALABEL:CorrosiveERGCode:8LSECTION15-REGULATORYINFORMATION

ousUnderHazardCommunicationStandard:

Lead-YESAntimony-YES

IngredientsListedonTSCAInventory:CERCLASection304HazardousSubstances:

YESLead–YESAntimony–YESArsenic–YES

RQ:NA*

RQ:1000poundsRQ:5000pounds

RQ:1pound

Arsenic-YES

*Reportingnotrequiredwhendiameterection302ExtremelyHazardousSubstance:EPCRASection313ToxicReleaseInventory:

Lead-CASNO:7439-92-1Antimony-CASNO:7440-36-0

Arsenic-CASNO:7440-38-2

SECTION16-OTHERINFORMATIONAllinformation,recommendations,andsuggestionsinthisMSDS,concerningourproductsarebasedontestsanddatabelievedtobereliable,heactualusebyothersisbeyondourcontrolitistheusersresponsibilitytodeterminethesafety,RD:GB12268-2005EQUALTOIMDGCode2004,第3204套修正案)THEINFORMATIONABOVEISBELIEVEDTOR,CONCORDEMAKESNOWARRANTYOFMERCHANTABILITYORANYOTHERWARRANTY,EXPRESSORIMPLIED,WITHRESPECTTOSUCHINFORMATION,ANDWEASSUMENOLIABILITYRESULTINGFROMITSUSE.

USERSSHOULDMAKETHEIROWN

ALTHOUGH

INVESTIGATIONSTODETERMINETHESUITABILITYOFTHEINFORMATIONFORTHEIRPARTICULARPURPOSES.

REASONABLEPRECAUTIONSHAVEBEENTAKENINTHEPREPARATIONOFTHEDATACONTAINEDHEREIN,ITISOFFEREDSOLELYFORYOURINFORMATION,CONSIDERATIONANDINVESTIGATION.

THISMATERIALSAFETYDATASHEETPROVIDESGUIDELINESFORTHE

SAFEHANDLINGANDUSEOFTHISPRODUCT;ITDOESNOTANDCANNOTADVISEONALLPOSSIBLESITUATIONS,THEREFORE,YOURSPECIFICUSEOFTHISPRODUCTSHOULDBEEVALUATEDTODETERMINEIFADDITIONALPRECAUTIONSAREREQUIRED.

NO.4ZHUIRIROAD,HI-TECHINDUSTRIALDEVELOPMENTAREA,XIANGFAN,HUBEI,CHINAPOSTCODE:441705Website::+2FAX:+5骆驼集团蓄电池销售有限公司

CAMELGROUPBATTERYTRADINGCO.,LTDMULTIMODALDANGEROUSGOODSFORM

ThisformmaybeusedasadangerousgoodsdeclarationasitmeetstherequirementsofSOLAS74,chapterVII,regulation5;MARPOL73/78,AnnexIII,regulation4andsection9oftheGeneralIntroductiontotheIMDGCode.1.

Shipper

ortdocumentnumber

CAMELGROUPBATTERYTRADINGCO.,.4ZHUIRIROAD,HI-TECHINDUSTRIALDEVELOPMENTAREA,XIANGFAN,HUBEI,CHINA,1/1

of

pages

r’sreference

tforwarder’sreference

r(tobecompletedbythecarrier)MAERSKLINE

T20715,WESTERNBYPASS,INDUSTRIALESTATE,GABORONE,BOTSWANAPOBOX149T:0F:ipmentiswithinthelimitationsprescribedfor:(Deletenon-applicable)

SHIPPER’SDECLARATION

Iherebydeclarethatthecontentsofthisconsignmentarefullyandaccuratelydescribedbelowbythepropershippingname,andareclassified,packaged,markedandlabeled/placardedandareinallrespectsinproperconditionfortransportaccordonalhandlinginformation

Emergencycontactperson:(紧急联系人)

//placeofloading

Emergencycontacttelephone:86-710-3344102(紧急联系人电话)WUHAN,/placeofdischargeDURBAN

ation

EMS

F-AS-B(紧急处理方式缩写)

GABORONE,BOTSWANANumberandkindofpackages;descriptionofgoods

(*seebottom)

ntinformation

grossweight28PLTS,UNITLOAD,PALLETBOX,CRATE

25761

netweight24781

Propershippingname:BATTERIES,WET,FILLEDWITHACIDelectricstorage

Technicalname(ifhave):ss(subrisk)Unno.:2794Packagegroup

Flashpoint(ifhave)

:III:NO:8

Marinepollutant(ifhave):NOEMS:

F-A,S-B

Packagequantity(Outerpackage):28PLTS,UNITLOAD,PALLETBOX,CRATE

Packagequantity(Interpackage):NO

NO.4ZHUIRIROAD,HI-TECHINDUSTRIALDEVELOPMENTAREA,XIANGFAN,HUBEI,CHINAPOSTCODE:441705Website::+2FAX:+5骆驼集团蓄电池销售有限公司

CAMELGROUPBATTERYTRADINGCO.,mber(s)nerSize&type1X20’ss(kg)KGSMSKU5863674CONTAINER/VEHICLEPACKINGCERTIFICATEIherebydeclarethatthegoodsdescribedabovehavebeenpacked/loadedintothecontainer/vehicleidentifiedaboveinaccordancewiththeapplicableprovisions.**MUSTBECOMPLETEDANDSIGNEDFORALLCONTAINER/VEHICLELOADSBYPERSONRESPONSIBLEFORPACKING/INGORGANIZATIONRECEIPTReceivedtheabovenumberofpackages/containers/trailersinapparentgoodorderandcondition,unlessstatedhereon:RECEIVINGORGANISATIONREMARKS:Haulier’company(OFSHIPPERCAMELGROUPBATTERYTRADINGCO.,CAMELGROUPBATTERYTRADINGCO.,/gnatureanddateName/aceanddatePlaceanddateSignatureofdeclarantDRIVER’SSIGNATURESignatureofdeclarant*DANGEROUSGOODS:

Youmustspecify:UNNo.,propershippingname/correcttechnicalname,IMOhazardclass(subrisk),Packaginggroup(whereassigned),Marine

pollutant,flashpoint(whereassigned),quantityofpackages,Grossweight,Netweightandobservethemandatoryrequirementsunderapplicable

purposestheIMDGCodesee5.4.1.1**ForthepurposesoftheIMDGCodesee5.4.2

NO.4ZHUIRIROAD,HI-TECHINDUSTRIALDEVELOPMENTAREA,XIANGFAN,HUBEI,CHINAPOSTCODE:441705Website::+2FAX:+5

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